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相关概念视频

Mechanisms of Membrane-bending01:15

Mechanisms of Membrane-bending

The living membranes are flexible due to their fluid mosaic nature; however, their bending into different shapes is an active process regulated by specific lipids and proteins. The membrane bending can be transient as seen in vesicles or stable for a long time as in microvilli. Cells regulate the size, location, and duration of the membrane curvature.
Membrane bending can happen due to intrinsic changes in lipid composition or extrinsic association with different proteins. The proteins involved...
Anionic Chain-Growth Polymerization: Mechanism01:04

Anionic Chain-Growth Polymerization: Mechanism

The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael acceptor.
Molecular Weight of Step-Growth Polymers01:08

Molecular Weight of Step-Growth Polymers

Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
Precipitate Formation and Particle Size Control01:16

Precipitate Formation and Particle Size Control

In precipitation gravimetry, the precipitating agent should react specifically or selectively with the analyte. While a specific reagent reacts with the analyte alone, a selective reagent can react with a limited number of chemical species.
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...

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相关实验视频

Updated: Jun 11, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
16:24

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water

Published on: August 2, 2012

在核心-外水凝纳米粒子中可调节的膨胀动力学.

D Gan1, L A Lyon

  • 1School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, USA.

Journal of the American Chemical Society
|August 2, 2001
PubMed
概括

核心外聚N-异烯胺 (p-NIPAm) 纳米粒子显示可调节的特性. 修改外 修改外 的方法

科学领域:

  • 聚合物科学 聚合物科学
  • 材料科学是一种材料科学.
  • 体科学是关于体的科学.

背景情况:

  • 热敏聚合物,如聚-N-异烯胺 (p-NIPAm),对于开发"智能"材料至关重要.
  • 核心外微凝架构为精确控制材料特性提供了一个平台.
  • 了解微凝中相变的动力学和热力学是它们应用的关键.

研究的目的:

  • 为了研究核心外p-NIPAm微凝中化学差异化对其相位过渡行为的影响.
  • 探索外修饰和热诱导崩的动力学之间的关系.
  • 为了确定表面修改是否能够控制微凝脱水率.

主要方法:

  • 种子和料沉聚合,用于合成核心的p-NIPAm微凝.
  • 不同扫描热量计 (DSC) 分析相位过渡热力学.
  • 质子核磁共振 (1H NMR) 和温度编程光子相关谱学 (TP-PCS) 用于研究动力学.

主要成果:

  • 用基甲基酸 (BMA) 对外的疏水性修改显著减缓了颗粒的崩.
  • 阶段过渡的热力学在很大程度上不受低水平的疏水性外改性影响.
  • 微凝脱落的速度主要取决于外的疏水性,而不是改变区域的厚度.

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Nanosponge Tunability in Size and Crosslinking Density
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Nanosponge Tunability in Size and Crosslinking Density

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Injection of Porcine Adipose Tissue-Derived Stroma Cells via Waterjet Technology
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Injection of Porcine Adipose Tissue-Derived Stroma Cells via Waterjet Technology

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相关实验视频

Last Updated: Jun 11, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
16:24

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water

Published on: August 2, 2012

Nanosponge Tunability in Size and Crosslinking Density
11:15

Nanosponge Tunability in Size and Crosslinking Density

Published on: August 4, 2017

Injection of Porcine Adipose Tissue-Derived Stroma Cells via Waterjet Technology
07:05

Injection of Porcine Adipose Tissue-Derived Stroma Cells via Waterjet Technology

Published on: November 23, 2021

结论:

  • 核心外架构对于设计具有可调节属性的智能凝是有效的.
  • 贝的表面修改足以控制微凝脱水动力学.
  • 在崩过程中形成表面皮肤层是脱落的速度限制步骤.