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双核Cu(A) 位点的几何学,还原潜力和重组能量,通过密度函数理论来研究

M H Olsson1, U Ryde

  • 1Contribution from the Department of Theoretical Chemistry, Lund University, Chemical Centre, P.O. Box 124, S-221 00 Lund, Sweden.

Journal of the American Chemical Society
|August 9, 2001
PubMed
概括

蛋白质中的二度铜 (A) 位点显示结构灵活性,在混合价值状态下有两个几乎相同的能量状态. 这种灵活性允许减少潜力的小变化,影响酶中的电子转移.

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