通过原子转移激素聚合在20°C的温度下,轻松合成明确的,生物相容的甲酸基共聚合物
E J Lobb1, I Ma, N C Billingham
1Biocompatibles, Frensham House Farnham Business Park, Weydon Lane Farnham, Surrey, GU9 8QL, UK.
Journal of the American Chemical Society
|August 9, 2001
概括
No abstract available in PubMed .
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Polymer Classification: Stereospecificity
Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
Complexation Equilibria: Overview
Complexation reactions take place when dative or coordinate covalent bonds form between metal ions and ligands. The compounds formed in these reactions are called coordination compounds. The number of bonds formed between the metal ion and the ligands is called its coordination number. Generally, most metal ions in an aqueous solution are solvated by water molecules and thus exist as aqua complexes.
The equilibrium constant of the complexation reaction is represented as the formation constant...
The equilibrium constant of the complexation reaction is represented as the formation constant...


