在冷温度下的天体物理冰中生产甲和有机分子
W A Schutte1, L J Allamandola, S A Sandford
1NASA/Ames Research Center, Moffett Field, CA 94035, USA.
概括
氨 (NH3) 对于冰冷环境中的甲 (H2CO) 反应至关重要,形成复杂的有机分子. 这些热反应发生在40-80K之间,对于理解彗星和星际化学有意义.
科学领域:
- 天体化学是天体化学.
- 化学动力学 化学动力学
- 行星科学 行星科学
背景情况:
- 甲 (H2CO) 是星际和彗星冰中的一个关键分子.
- 了解复杂有机分子的形成途径对于天体生物学至关重要.
- 低温冰化学在天体的组成中起着重要作用.
研究的目的:
- 为了研究热促进的甲反应在冷冰中的作用.
- 为了确定氨 (NH3) 对甲反应的影响.
- 确定这些反应的产物及其对彗星和恒星间化学的影响.
主要方法:
- 红外光谱学被用来研究含有H2CO,H2O,CH3OH,CO和NH3的冰.
- 在冷冰矩阵中研究了反应.
- 进行了光谱分析,以确定反应产物和起始温度.
主要成果:
- 少量的NH3 (NH3/H2CO>=0.005) 可以显著地将H2CO转化为复杂有机物 (>40%).
- H2CO反应需要NH3的存在,并开始在40-80K之间.
- 形成了五种不同的产品,主要是聚氧甲衍生物,与辐射产品不同.
结论:
- 热H2CO反应,由NH3催化,是彗星和星际冰中的复杂有机物的可行来源.
- 产品分布对初始冰的组成敏感,作为彗星历史的标志物.
- 彗星p/哈雷昏迷中的约3%的有机物可能源于这些热反应.
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