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Updated: Jul 15, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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通过半三明治Mo(III) /Mo(IV) 配对控制的 styrene 的极端聚合:所有基本机制都是可能的

E Le Grognec1, J Claverie, R Poli

  • 1Laboratoire de Synthèse et d'Electrosynthèse Organométalliques, Faculté des Sciences Gabriel, Université de Bourgogne, 6 Boulevard Gabriel, 21000 Dijon, France.

Journal of the American Chemical Society
|September 27, 2001
PubMed
概括

密度函数计算指导了通过稳定的自由基聚合 (SFRP) 或原子转移激素聚合 (ATRP) 进行受控的styrene聚合的复合物的选择. 这些复合物使控制的聚合成为可能,其中一些根据反应条件表现出催化链转移.

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