海洋沉积物的有机碳组成:氧气暴露对石油产生的潜在影响
Y Gélinas1, J A Baldock, J I Hedges
1School of Oceanography, Box 357940, University of Washington, Seattle, WA 98195-7940, USA. ygelinas@alcor.concordia.ca
概括
沉积式有机物 (OM) 暴露在氧气中较短的时间,就像沿海地区一样,含有更多的非蛋白质基碳,这是石油产生的关键指标. 在深海沉积物中常见的较长时间的氧气暴露会减少这种易于石油的碳.
科学领域:
- 地质化学 地质化学
- 有机地化学 有机地化学
- 沉积地质的地质学
背景情况:
- 传统上,厌氧条件与石油来源岩石生成有关.
- 沉积物氧化还原条件对新鲜有机物 (OM) 组成的影响尚不清楚.
研究的目的:
- 评估在现场接触氧气条件的时间如何影响累积OM的组成.
- 调查OM组成和石油生产潜力之间的关系.
主要方法:
- 使用了固态13C核磁共振 (NMR) 光谱学.
- 分析了13C NMR光谱,以量化蛋白质和非蛋白质结构中的基碳.
主要成果:
- 在氧化物暴露时间和非蛋白质基 (alkylNP) 碳丰度之间观察到一个反向关系.
- 短时间接触氧气的沿海沉积物比长时间暴露的深海沉积物有显著更高的基NP碳度.
- 富含基NP的样本含有聚甲成分,这是I型油页岩的特征.
结论:
- 氧化物暴露的持续时间直接影响海洋沉积物中OM的质量和产油潜力.
- 在不同的氧化还原条件下了解OM的组成对于石油勘探至关重要.
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