压力诱导的无形化和无形-无形过渡在密集的多孔中
S K Deb1, M Wilding, M Somayazulu
1Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai 400 085, India.
Nature
|December 6, 2001
概括
孔隙薄膜的压缩会导致10 GPa以上的无形化. 在解压时,发生了独特的无形相转换,反映了水.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术 纳米技术
背景情况:
- 是电子和光伏的关键材料.
- 大量在压力下过渡到金属相.
- 纳米晶体表现出独特的压力诱导的结构变化.
研究的目的:
- 研究在压缩下多孔的行为.
- 在多孔膜中表征压力诱导的无形化.
- 探索由此产生的无形相的减压行为.
主要方法:
- 在多孔膜上的压缩实验.
- 拉曼光谱用于结构分析.
- 高压测量超过10 GPa.
主要成果:
- 多孔经历了10 GPa以上的压力诱导的无形化.
- 形成一个高密度的无形相.
- 在解压时,它转化为低密度的无形相.
结论:
- 与散装相比,多孔具有明显的无形化和解压行为.
- 观察到的无形-无形过渡表明超冷中的液相类似过渡.
- 这一发现为在极端条件下的复杂相位图提供了新的见解.
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