基于分子的电子可切换道连接装置
C P Collier1, J O Jeppesen, Y Luo
1California NanoSystems Institute and the Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095-1569, USA.
Journal of the American Chemical Society
|December 14, 2001
概括
研究人员开发的分子电子器件使用可双相稳定的catenanes,伪,和rotaxanes. 这些分子开关证明了可调节的导电性,为新型电子元件铺平了道路.
科学领域:
- 分子电子学分子电子学
- 超分子化学 超分子化学
- 材料科学是一种材料科学.
背景情况:
- 分子开关对于开发先进的电子设备至关重要.
- 在分子层面控制导电性是纳米技术的一个关键挑战.
研究的目的:
- 使用分子单层制造和表征固态道连接装置.
- 研究分子结构,薄膜特性和设备性能之间的关系.
主要方法:
- 制造Langmuir Blodgett分子单层的可比化 [2]catenane,可比化 [2]pseudorotaxane和单站 [2]rotaxane.
- 固态道连接器件中电流-电压 (I-V) 响应的表征.
- 分析结构-属性相关性,包括溶液相动态和晶体学域结构.
主要成果:
- 所有制造的设备都表现出非容量性的歇斯底里电流电压响应.
- 设备在高和低导电状态之间切换,表明分子切换行为.
- 没有分子单层的控制装置没有显示出这种反应.
结论:
- 分子单层的双稳定catenanes,伪,和rotaxanes可以作为固态开关.
- 设备的性能受到分子结构,动力学和膜形态学的影响.
- 这些发现表明了超分子系统在分子电子学中的潜力.
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