实验确定Cr-C(2)Cl(4) 键解离在Cr(CO)(5)(C(2)Cl(4) 中的Cr-C(2)Cl(4) 键解离:量化金属-烯结合相互作用

D L Cedeño1, E Weitz

  • 1Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113, USA.

概括

在有机金属复合体中,Cr-C键被烯变形所削弱,而不仅仅是电子相互作用. 这种变形能量显著影响金属-烯结合强度.

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