新的酸表面活性剂用于二氧化碳
Jason S Keiper1, Ruma Simhan, Joseph M DeSimone
1Forschungszentrum Jülich GmbH, Institut für Festkörperforschung, D-52425 Jülich, Germany.
Journal of the American Chemical Society
|February 28, 2002
概括
阳离子酸盐表面活性剂在二氧化碳中自组合成微乳液,使其能够大量吸收水分. 微角中子散射证实了这些独特的表面活性剂/水/CO2溶液中纳米尺度聚合物的形成.
科学领域:
- 超分子化学 超分子化学
- 合体和表面科学科学
- 绿色化学是一种绿色化学.
背景情况:
- 表面活性剂对于稳定非水系统至关重要.
- 二氧化碳 (CO2) 是一种具有独特性质的环保溶剂.
- 微乳液提供增强的可溶性和反应环境.
研究的目的:
- 研究二氧化碳中离子酸盐表面活性剂的自我组装.
- 为了确定这些表面活性剂形成CO2中的水微乳液的能力.
- 为了描述形成的聚合物的结构.
主要方法:
- 离子酸表面活性剂的合成,具有不同的链结构.
- 使用水,二氧化碳和表面活性剂制备微乳液.
- 用于结构分析的小角度中子散射 (SANS).
主要成果:
- 阳离子酸盐表面活性剂在CO2中成功自我组装.
- 具有两个化链或一个化链和一个碳化合物链的表面活性剂促进了显著的水吸收.
- SANS证实了纳米尺度聚合物的形成,表明了微乳液结构.
结论:
- 阳离子酸盐表面活性剂在制造二氧化碳中的水微乳液方面是有效的.
- 这些微乳液在超临界CO2中表现出显著的含水能力.
- 这项研究展示了利用二氧化碳作为反应介质的新方法.
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