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使用平衡同位素效应来检测分子内OH/OH键:结构和溶剂效应

Thomas E Vasquez1, Jon M Bergset, Matthew B Fierman

  • 1Department of Chemistry, Pomona College, 645 North College Avenue, Claremont, CA 91711, USA.

Journal of the American Chemical Society
|March 21, 2002
PubMed
概括

在不同的溶剂中,分子内键表现出相反的同位素转移信号. 乳更喜欢分子间的键,而化-d(5) 放大了配置分配的变化.

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