在固态状态下56个锡原子的裸体集群
1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA.
Journal of the American Chemical Society
|March 28, 2002
概括
研究人员在一个新的--化合物中发现了56个原子的巨大,孤立的锡集群. 这一发现代表了固态中最大的主群裸体集群,不包括富勒伦.
科学领域:
- 固态化学 固态化学
- 无机化学 无机化学 无机化学
- 材料科学是一种材料科学.
背景情况:
- 由于其独特的电子和结构性质,锡集群具有显著的兴趣.
- 之前的研究集中在较小的锡集群或被封装在其他材料中的锡集群上.
研究的目的:
- 合成和描述含有大型锡集群的新型三元化合物.
- 为了研究这些新发现的锡集群的结构和结合.
主要方法:
- 在800°C的温度下直接融合元素,和锡.
- 单晶X射线衍射用于结构确定Ba(16) Na(204) Sn(310) 化合物.
主要成果:
- 发现了孤立的,巨大的锡集群 ([Ba(4)@Sn(56)](36-)) 由56个锡原子组成,类似于凸的富勒伦.
- 星团由四个面接融合的五角形十二面体组成,并由四个离子稳定.
- 这代表了在固态中发现的最大的主群裸体集群,不包括富勒伦.
- 在该结构中还发现了其他锡集群,包括Sn 16 n 和Sn 8 .
结论:
- Ba(16) Na(204) Sn(310) 的合成提供了一条通往固态中新型的大型主群集群的途径.
- 发现的[Ba(4)@Sn(56)](36-) 团扩大了我们对团化学的理解,超越了富勒伦.
- 这项工作为探索复杂的锡基材料的性能和潜在应用开辟了新的途径.
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