气溶形成:来自有机蒸汽的大气颗粒
Colin D O'Dowd1, Pasi Aalto, Kaarle Hmeri
1Division of Atmospheric Sciences, Department of Physical Sciences, PO Box 64, University of Helsinki, 00014 Helsinki, Finland. colin.odowd@cmas.demon.co.uk
Nature
|April 5, 2002
概括
来自森林的新形成的气溶颗粒主要是有机的,包括cis-pinonic acid和pinic acid. 这些化合物起源于氧化烯,影响云形成和气候.
科学领域:
- 大气化学 大气化学
- 气候科学 气候科学
- 生物地质化学生物地质化学
背景情况:
- 森林释放挥发性有机化合物 (VOCs),可以形成大气颗粒.
- 气溶颗粒影响云凝聚核 (CCN) 的形成和全球气候.
- 新形成的森林气溶的化学成分尚不清楚.
研究的目的:
- 为了确定森林地区新形成的气溶颗粒的化学成分.
- 为了确定驱动这些颗粒的生产的前体物种.
- 了解它们作为云凝聚核的作用对气候的影响.
主要方法:
- 对3-5纳米直径的气溶颗粒在森林地区收集的分析.
- 使用先进的化学分析技术识别有机物种.
- 追溯颗粒成分回归到生物源烯蒸汽的氧化过程.
主要成果:
- 新形成的气溶颗粒主要由有机物种组成.
- 确定的主要化合物包括cis-pinonic酸和pinic酸.
- 这些有机物种是森林树冠发出的烯氧化的结果.
结论:
- 新形成的森林气溶的主要成分是氧化有机化合物.
- 氧化产物是这些环境中新粒子形成的主要驱动因素.
- 了解这种有机气溶成分对于准确的气候建模至关重要.
相关概念视频
States of Water
Water exists in any one of the three classical states: solid (ice), liquid (water), and gas (steam or water vapor). The state of water depends on i) the intermolecular forces that draw molecules together and ii) the kinetic energy that leads to movements that pull them apart.
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
Water freezes when the intermolecular forces are greater than the kinetic energy. Unlike most other substances, water is less dense in its solid state than in its liquid state. This is because each water molecule can form...
Vaporization
The physical form of a substance changes by changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. For vaporization to occur, kinetic energy must be greater than the intermolecular forces that keep molecules bonded. The amount of energy needed to vaporize a quantity of liquid at a given pressure and a constant temperature is called the heat of vaporization. When...
Vapor Pressure
When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules move randomly about, they will occasionally collide with the surface of the condensed phase, and in some cases, these collisions will result in the molecules re-entering the condensed phase. The change from the gas phase to the liquid is called condensation. When the rate of condensation becomes equal to the rate of vaporization, neither the amount of the liquid nor the amount of the vapor...
Colloids
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
Atomic Absorption Spectroscopy: Atomization Methods
Atomic Absorption Spectroscopy (AAS) atomizes samples through flame atomization or electrothermal atomization. Flame atomization typically involves a nebulizer and spray chamber assembly to combine the sample with a fuel–oxidant mixture, creating a fine aerosol mist that enters a burner. Typically, the fuel and oxidant are combined in an approximately stoichiometric ratio. However, for atoms that are easily oxidized, a fuel-rich mixture may be more advantageous. Only about 5% of the aerosol...
The Colloidal State
The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called the...


