一种稳定的烯与和碳化合物的性反应
Daniel F Moser1, Todd Bosse, Jordan Olson
1Organosilicon Research Center, University of Wisconsin, Madison, Wisconsin 53706, USA.
Journal of the American Chemical Society
|April 19, 2002
概括
研究人员通过使用稳定的烯和各种碳化合物合成了新型的dysilanes. 这项研究提出了一种性相互作用机制驱动着迪西兰的形成,这种机制得到了结构分析的支持.
科学领域:
- 有机化学 有机化学
- 合成有机化学 合成有机化学
背景情况:
- 稳定烯是化学中的反应性中间体.
- 环氧碳是有机合成中的多功能试剂.
研究的目的:
- 从稳定的烯和多种类型的碳化合物中合成新型的dysilanes.
- 为了阐明迪西兰形成的反应机制.
主要方法:
- 烯1 (N,N'-di-tert-butyl-1,3-diaza-2-silacyclopent-4-en-2-ylidene) 与碳化合物 (CCl4,CHCl3,CH2Cl2,化,甲) 的反应.
- 合成的dysilanes的表征.
- 关键中间体的X射线晶体结构的确定.
主要成果:
- 从烯1与各种环氧碳素的反应中成功合成多个disilate.
- 作为关键步骤,证据支持烯和碳之间的初始性相互作用.
- 一个disilane产品的结构确认.
结论:
- 稳定的烯1是合成各种烯的可行前体.
- 一种性相互作用机制被提议用于形成这些dysilanes.
- 合成方法为含有的化合物提供了一条新的途径.
相关概念视频
Chemical Reactions
A chemical reaction is a process by which the bonds in the atoms of substances are rearranged to generate new substances. Matter cannot be created or destroyed in a chemical reaction—the same type and number of atoms that make up the reactants are still present in the products. Merely, the rearrangement of chemical bonds produces new compounds.
Chemical Reactions Rearrange Atoms into New Substances
A chemical reaction takes starting materials—the reactants—and changes them into different...
Chemical Reactions Rearrange Atoms into New Substances
A chemical reaction takes starting materials—the reactants—and changes them into different...
Chemical Reactions
A balanced chemical equation provides the information of chemical formulas of the reactants and products involved in the chemical change. A reaction’s stoichiometry helps predict how much of the reactant is needed to produce the desired amount of product, or in some cases, how much product will be formed from a specific amount of the reactant.
The relative amounts of reactants and products represented in a balanced chemical equation are often referred to as stoichiometric amounts. However, in...
The relative amounts of reactants and products represented in a balanced chemical equation are often referred to as stoichiometric amounts. However, in...
Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes
The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified petroleum gas (LPG), fuel oil, gasoline, diesel fuel, and...
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified petroleum gas (LPG), fuel oil, gasoline, diesel fuel, and...
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Pericyclic Reactions: Introduction
Pericyclic reactions are organic reactions that occur via a concerted mechanism without generating any intermediates. The reactions proceed through the movement of electrons in a closed loop to form a cyclic transition state, where rearrangement of the σ and π bonds yields specific products.
Pericyclic reactions can be classified into three categories: electrocyclic reactions, cycloaddition reactions, and sigmatropic rearrangements. Electrocyclic reactions and sigmatropic rearrangements are...
Pericyclic reactions can be classified into three categories: electrocyclic reactions, cycloaddition reactions, and sigmatropic rearrangements. Electrocyclic reactions and sigmatropic rearrangements are...
Types of Chemical Reactions: Exchange and Reversible
An exchange reaction is a chemical reaction in which both synthesis and decomposition occur, chemical bonds are both formed and broken, and chemical energy is absorbed, stored, and released.
A special kind of exchange reaction is the oxidation-reduction reaction, or the redox reaction. These reactions involve the transfer of electrons from one compound to another. The electrons in these reactions commonly come from hydrogen atoms, which consist of an electron and a proton. A molecule gives up a...
A special kind of exchange reaction is the oxidation-reduction reaction, or the redox reaction. These reactions involve the transfer of electrons from one compound to another. The electrons in these reactions commonly come from hydrogen atoms, which consist of an electron and a proton. A molecule gives up a...


