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相关概念视频

Le Chatelier's Principle: Changing Volume (Pressure)02:32

Le Chatelier's Principle: Changing Volume (Pressure)

For gas-phase equilibria, changes in the concentrations of reactants and products can occur with altered volume and pressure. The partial pressure, P, of an ideal gas is proportional to its molar concentration, M.
Ziegler–Natta Chain-Growth Polymerization: Overview01:17

Ziegler–Natta Chain-Growth Polymerization: Overview

Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta catalyst, high molecular...
Expansion and Contraction in Masonry Walls01:19

Expansion and Contraction in Masonry Walls

Masonry walls are subject to slight expansion and contraction due to variations in temperature and moisture. Thermal movement in masonry is relatively straightforward to measure and plan for. On the other hand, moisture movement poses more of a challenge. New clay masonry units typically absorb water and expand over time under normal environmental conditions. Conversely, new concrete masonry units tend to shrink as they lose the excess moisture acquired during their production process.
To...
Pozzolans01:21

Pozzolans

Pozzolans are siliceous or aluminous materials blended with Portland cement. They interact with the calcium hydroxide produced during the hydration of Portland cement and contribute to improved strength and durability of concrete. The pozzolanic activity, a measure of a pozzolan's effectiveness, is typically assessed using the strength activity index, as defined in ASTM C 618-93, which calculates the ratio of the compressive strength of cement mixtures with and without pozzolan.
Fly ash is a...

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相关实验视频

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Experimental Strategies to Bridge Large Tissue Gaps in the Injured Spinal Cord after Acute and Chronic Lesion
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Experimental Strategies to Bridge Large Tissue Gaps in the Injured Spinal Cord after Acute and Chronic Lesion

Published on: April 5, 2016

纳托利特家族中石的压力诱导体积膨胀.

Yongjae Lee1, Thomas Vogt, Joseph A Hriljac

  • 1Physics Department, Brookhaven National Laboratory, Upton, New York 11973-5000, USA. yollee@bnl.gov

Journal of the American Chemical Society
|May 9, 2002
PubMed
概括

高压会导致具有纳托利特框架拓的石通过吸收水而膨胀,形成新的"超化"相. 这种结构变化有所变化,导致压力下独特的晶体化学.

科学领域:

  • 矿物学和结晶学研究.
  • 在极端条件下的材料科学.
  • 地质化学和石油学.

背景情况:

  • 具有纳托利特框架拓的热利特,包括纳托利特,美索利特,斯科莱西特和加洛酸盐模拟物,具有独特的结构性质.
  • 了解它们在高压下的行为对于各种地质和材料科学应用至关重要.

研究的目的:

  • 为了研究纳托利特框架泽奥利特的高压晶体化学.
  • 描述这些热石的结构反应,包括体积变化和相变,高达5.0GPa.
  • 阐明压力诱导体积膨胀和"超水"背后的机制.

主要方法:

  • 用同步 X 射线衍射测量了粉末衍射模式.
  • 使用钻石形电池实现了高压.
  • 为了分析结构变化,特别是纳托莱特,进行了瑞特维尔德提炼.

主要成果:

  • 所有研究的热石在水静态条件下,在不改变框架拓的情况下,都显示出0.8至1.5GPa之间的突然体积膨胀.
  • 由于选择性水吸附,纳托利特形成了一个"超化"阶段 (Na(16) Al(16) Si(24) O(80).32H(2) O),形成了水纳米管.
  • 石表现出压力诱导的秩序-混乱过渡,斯科莱石表现出可逆的部分无形化,而酸模拟物显示出压力释放后保留的3D扩张.

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Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5
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Experimental Strategies to Bridge Large Tissue Gaps in the Injured Spinal Cord after Acute and Chronic Lesion
09:14

Experimental Strategies to Bridge Large Tissue Gaps in the Injured Spinal Cord after Acute and Chronic Lesion

Published on: April 5, 2016

Synthesis of Zeolites Using the ADOR (Assembly-Disassembly-Organization-Reassembly) Route
08:26

Synthesis of Zeolites Using the ADOR (Assembly-Disassembly-Organization-Reassembly) Route

Published on: April 3, 2016

Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5
09:46

Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5

Published on: August 25, 2016

结论:

  • 具有纳托利特框架拓的热质石表现出各种高压行为,包括异常的胀和相位过渡.
  • 选择性吸水在纳石和中石的"超化"和扩张中起着关键作用.
  • 观察到的现象突出了这些材料在极端条件下的复杂晶体化学和它们对新材料性质的潜力.