一个智能接接头:在聚合物/金属接口上对粘附的热控制
Sureurg Khongtong1, Gregory S Ferguson
1Department of Chemistry and Materials Science, Lehigh University, Bethlehem, Pennsylvania 18015-3172, USA.
Journal of the American Chemical Society
|June 20, 2002
概括
研究人员为聚合物/金属接口开发了"智能"粘合,这种粘合与温度发生可逆变化. 这种响应性材料利用1,4-聚丁的弹性来进行可调节的粘附控制.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 表面化学 表面化学
背景情况:
- 粘附科学跨越多个学科,包括物理,化学,工程和医学.
- 有许多方法可以增强或抑制接口上的粘附.
- 响应性材料通过可调节的特性提供了先进的应用.
研究的目的:
- 在聚合物/金属 (氧化物) 接口上报告新的"智能"粘附.
- 为了证明可逆的粘附变化响应温度.
- 探索积极控制材料性能的潜力.
主要方法:
- 在1,4-聚乙烯/金属 (氧化物) 接口上研究粘附.
- 利用温度作为刺激来改变粘附.
- 分析了弹性的作用在温度依赖的粘附.
主要成果:
- 经过证明的可逆粘附,随着温度变化而增加或减少.
- 观察到温度的依赖是由1,4-聚丁的弹性决定的.
- 发现这种界面行为反映了聚合物与水的相互作用.
结论:
- 开发了一种具有温度响应特性的"智能"粘合系统.
- 突出了弹性的潜力,在创造可调节的粘合力方面.
- 开辟了设计具有主动控制性质的先进响应材料的途径.
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