在叶片和柱状半相之间重新进入的同位素相
Urszula Pietrasik1, Jadwiga Szydłowska, Adam Krówczyński
1Chemistry Department, Warsaw University, Laboratory of Dielectrics and Magnetics, Al. Zwirki i Wigury 101, 02-089 Warsaw, Poland.
Journal of the American Chemical Society
|July 26, 2002
概括
合成的 (II) 复合物与分子内键具有独特的液晶特性. 首次在柱状和状阶段之间观察到同源回入阶段.
科学领域:
- 协调化学 协调化学
- 材料科学 材料科学 材料科学
- 液晶是一种液晶.
背景情况:
- 合成了四方牙中的cis-enaminoketone Ni (II) 复合物.
- 引入了分子内键,以修改分子结构和特性.
研究的目的:
- 研究分子形状和结对Ni (II) 复合物的液晶性行为的影响.
- 在合成化合物中探索新的相序列.
主要方法:
- 合成四牙的cis-enaminoketone Ni (II) 复合物.
- 分子结构和相位行为的表征.
主要成果:
- 具有分子内键和基终端链的复合体显示了一个不常见的相序列:Iso-D(h) -Iso(re) -SmA.
- 首次观察到同位素再进入 (Iso(re)) 阶段,分离柱状 (D) 和片状 (SmA) 阶段.
结论:
- 分子内键显著影响Ni (II) 复合物的中产物特性.
- 在柱状和叶片状相之间发现同otropic回入相,为液晶相转换提供了新的见解.
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