对哈西 (108元素) 的化学研究
Ch E Düllmann1, W Brüchle, R Dressler
1Departement für Chemie und Biochemie, Universität Bern, CH-3012 Bern, Switzerland.
Nature
|August 23, 2002
概括
研究人员在化学上描述了 (元素108) 的七个原子,发现其属性与预测一致. 这证实了的存在.
科学领域:
- 核化学 核化学 核化学
- 重元素中的相对论效应
- 定期趋势 周期性趋势
背景情况:
- 周期表对元素属性进行了分类,但相对论效应挑战了重型交叉性元素的趋势.
- 元素104-107表现出由相对论效应影响的多种化学行为.
- 元素108 () 的行为以前没有得到证实.
研究的目的:
- 为了化学表征108元素 ().
- 为了确定是否遵循周期趋势,尽管相对论效应.
- 为了比较的化学特性与其更轻的同类物,.
主要方法:
- -26和加利福尼亚-248的融合反应产生同位素 (269) Hs和 (270) Hs.
- 检测到的七个原子的化学分离和表征.
- 将哈西氧化成一种挥发性氧化物 (大概是HsO4),并测量其吸附度.
主要成果:
- 原子成功合成并化学分离.
- 在实验条件下,哈西很容易形成一种挥发性氧化物,HsO4.
- HsO4的吸附度与OsO4的吸附度相当,表明具有类似的化学特性.
结论:
- 哈西 (108元素) 的化学特性与相似.
- 哈西对其在周期表第8组的地位表现得如期.
- 这项研究证实了周期表对的预测能力,尽管有相对论效应.
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