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质子合电子转移与原子转移相比,在/多,甲氧/甲醇和/自我交换反应中

James M Mayer1, David A Hrovat, Jennie L Thomas

  • 1Contribution from the Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, USA. mayer@chem.washington.edu

Journal of the American Chemical Society
|September 13, 2002
PubMed
概括

密度函数理论的计算揭示了交换反应的独特机制. /多和甲氧/甲醇反应通过原子转移 (HAT) 进行,而/则涉及质子合电子转移 (PCET).

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