欧洲富勒化铁磁体Eu(6)C(60) 的磁性结构
Irene Margiolaki1, Serena Margadonna, Kosmas Prassides
1School of Chemistry, Physics, and Environmental Science, University of Sussex, Brighton BN1 9QJ, UK.
Journal of the American Chemical Society
|September 19, 2002
概括
研究人员在14K以下的分子铁磁体Eu6C60中观察到磁性散射. 这种富勒烯材料表现出以双价欧为中心的体中心立方磁结构,这表明轨道杂交驱动其属性.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学 材料科学 材料科学
- 磁力学 磁力学 是一种
背景情况:
- 基于富勒烯的材料正在探索其独特的电子和磁性特性.
- 分子铁磁铁为先进的应用提供可调节的特性.
- 了解结构和磁力之间的相互作用至关重要.
研究的目的:
- 在Eu6C60.0.中直接观察和描述磁性散射.
- 为了确定这种富勒基铁磁体的磁性结构和特性.
- 调查轨道杂交对其导电和磁性行为的作用.
主要方法:
- 利用粉末中子衍射来直接观察磁散射.
- 进行的测量低于观察到的基里温度 (大约14K).
主要成果:
- 证实了Eu6C60中的铁磁性,其基里温度约为14K.
- 确定了具有磁矩为7.1的双价欧 (Eu2+),每原子的波尔磁子.
- 确定磁体结构为以身体为中心的立方体.
- 观察到Eu2+和C60单位之间的密切接触,表明轨道杂交.
结论:
- 欧6C60的磁性归因于双价欧离子.
- 欧2+和C60之间的轨道杂交是材料导电性和磁性特性的关键因素.
- Eu6C60是一种有前途的富勒基分子铁磁体.
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