片在污染的河流中的起源
Gerhard Furrer1, Brian L Phillips, Kai-Uwe Ulrich
1Institute of Terrestrial Ecology, Eidgenössische Technische Hochschule Zürich, Grabenstrasse 3, CH-8952 Schlieren, Switzerland. furrer@ito.umnw.ethz.ch
概括
采矿污染流域的酸性,和重金属. 这些污染物很可能是从聚合的氧化氧化片中形成的,特别是在受影响的流中发现的Al13纳米集群.
科学领域:
- 环境化学环境化学
- 地质化学 地质化学
- 水的质量 水的质量
背景情况:
- 采矿活动破坏了广大土地面积,导致流域污染.
- 酸性矿山废水和土壤污染了水体的酸性,和重金属.
- 污染物以氧化氧化片的形式沉,以悬浮固体的形式在流中运输.
研究的目的:
- 调查矿业污染的河流中的氧化氧化片的组成和来源.
- 为了确定负责形成和污染物运输的特定物种.
主要方法:
- 分析了9个受采矿影响的河流的样本.
- 使用先进技术对氧化氧化片的表征.
- 在中识别了西隆-凯金多氧化物AlO4Al12(OH) 24(H2O) 12(7+) ((aq) (Al13).
主要成果:
- 所有分析的都含有不同的Al ((O) 4) 中心.
- 这些中心在结构上与Al13纳米团中发现的类似.
- 有证据表明,Al13纳米集群是观察到的氧化氧化片的前体.
结论:
- 13纳米集群很可能是矿业污染的流域中氧化片的形成的原因.
- 这些在吸附污染物的运输中起着重要作用.
- 了解形成对于减轻采矿相关的水污染至关重要.
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