在金纳米管膜中的电调节分子运输
Sang Bok Lee1, Charles R Martin
1Department of Chemistry, Center for Research at the Bio/Nano Interface, University of Florida, Gainesville, FL 32611-7200, USA.
Journal of the American Chemical Society
|October 3, 2002
概括
研究人员用金纳米管制造了合成膜,用于控制分子运输. 应用电潜能可逆地切换了膜.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 电化学 电化学 电化学
背景情况:
- 合成膜可以控制运输.
- 黄金纳米管提供纳米级导管.
- 运输的电调节是一个新兴的领域.
研究的目的:
- 开发一种用于通过合成膜电调节中性分子运输的方法.
- 为了利用金纳米管进行可调节的分子运输.
- 研究离子表面活性剂在控制膜性质中的作用.
主要方法:
- 嵌入单分散金 (Au) 纳米管 (<1nm内径) 的合成膜的制造.
- 对Au纳米管膜的电潜的应用.
- 使用阳离子表面活性剂来改变纳米管的疏水性.
- 监测中性疏水分子穿过膜的运输.
主要成果:
- 金纳米管为分子和离子运输提供管道.
- 阳性潜能诱导的阳离子表面活性剂吸附使纳米管内部变得疏水.
- 当纳米管是疏水的时,疏水分子的运输会得到增强.
- 负潜力会驱逐表面活性剂,恢复更多的水友状态并调节运输.
结论:
- 使用AU纳米管膜证明了一种用于中性分子运输的可逆电调节的新方法.
- 该系统允许通过电气手段对疏水分子的通过进行可调节的控制.
- 这项技术有可能用于分离,传感和控制释放系统.
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