形成一个新的晶体酸盐结构,通过在分层的八酸盐上接种dialkoxysilyl基
Dai Mochizuki1, Atsushi Shimojima, Kazuyuki Kuroda
1Department of Applied Chemistry, Waseda University, Shinjuku-ku, Tokyo 169-8555, Japan.
Journal of the American Chemical Society
|October 10, 2002
概括
二氧化二西兰与多层酸盐反应,形成新的晶体结构. 这种软化学路径为设计具有独特的五个成员环的先进酸框架提供了一种新方法.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 纳米技术 纳米技术
背景情况:
- 层状酸盐具有可以功能化的间层醇组.
- 设计新酸框架对于先进的材料应用至关重要.
研究的目的:
- 为了探索dialkoxydichlorosilanes和八酸盐之间的反应.
- 开发一种新的软化学路径,用于构建晶酸框架.
主要方法:
- 在八酸盐中,dialkoxydichlorosilanes与中间层silanol群的反应.
- 由此产生的晶状酸盐结构的特征.
主要成果:
- dialkoxydichlorosilanes与西兰醇组的完整反应.
- 形成一个新的晶体酸盐结构,在酸盐层的两侧有规律排列的五个环.
结论:
- 介绍dialkoxysilyl组为酸框架设计创造了一种新的方法.
- 软化学合成使得新型结晶酸盐材料的制造成为可能.
相关概念视频
Ionic Bonding and Electron Transfer
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Lewis Structures of Molecular Compounds and Polyatomic Ions
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Ionic Crystal Structures
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Acid Halides to Carboxylic Acids: Hydrolysis
Hydrolysis of acid halides is a nucleophilic acyl substitution reaction in which acid halides react with water to give carboxylic acids. The reaction occurs readily and does not require acid or a base catalyst.
As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic acid...
As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic acid...
Preparation of Acid Anhydrides
One of the methods for preparing symmetrical or unsymmetrical acid anhydrides involves the treatment of acid chlorides with the sodium salt of carboxylic acids. The reaction proceeds via a nucleophilic acyl substitution.
The carboxylate ion acts as a nucleophile that attacks the carbonyl carbon of the acid chloride to form a tetrahedral intermediate. Subsequently, the re-formation of the carbonyl group with the loss of the chloride ion as a leaving group leads to the formation of an acid...
The carboxylate ion acts as a nucleophile that attacks the carbonyl carbon of the acid chloride to form a tetrahedral intermediate. Subsequently, the re-formation of the carbonyl group with the loss of the chloride ion as a leaving group leads to the formation of an acid...
Diazonium Group Substitution: –OH and –H
Nitrous acid, a weak acid, is prepared in situ via the reaction of sodium nitrite with a strong acid under cold conditions. This nitrous acid prepared in situ reacts with primary arylamines to form arenediazonium salts. Such reactions are known as diazotization reactions. As shown in Figure 1, the formation of arenediazonium salts begins with the decomposition of nitrous acid in an acidic solution to give nitrosonium ions.


