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Nanomoulding of Functional Materials, a Versatile Complementary Pattern Replication Method to Nanoimprinting
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对具有周期结构的混合纳米复合材料的新方法

Jiguang Zhang1, Neil Coombs, Eugenia Kumacheva

  • 1Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada.

Journal of the American Chemical Society
|December 6, 2002
PubMed
概括

研究人员开发了一种新的"自下而上"方法,使用混合聚合物半导体微球来创建光学响应的纳米复合材料. 这种技术使得纳米粒子在光子晶体应用中能够精确地排列.

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Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...