第一个silastannene>si=sn<:一个由较重的14组元素组成的新的双键系统
Akira Sekiguchi1, Rika Izumi, Vladimir Ya Lee
1Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. sekiguch@staff.chem.tsukuba.ac.jp
Journal of the American Chemical Society
|December 12, 2002
概括
研究人员合成了一种具有独特Si=Sn双键的新型-锡化合物. 这种高度反应性的分子表现出通过X射线结晶学确认的跨曲结构,为-锡化学提供了洞察力.
科学领域:
- 有机金属化学 有机金属化学
- -锡化学 -锡化学
- 材料科学 材料科学 材料科学
背景情况:
- 二甲基化合物及其独特的结合特性具有显著的兴趣.
- 低价值化合物的合成和表征已经扩大.
- 在主要组化学中探索新的结合模式至关重要.
研究的目的:
- 为了合成和描述一种具有-锡 (Si=Sn) 双键的新型化合物.
- 研究合成的西拉斯坦的结构性质.
- 为了探索Si=Sn双键的反应性和电子性质.
主要方法:
- 双[二-三-基基基基基基基基基基基基基基基基基基基基基基基基基基基基基基基基基基基基基的反应.
- 通过X射线晶体学对产品进行隔离和表征.
- 理论计算以支持实验发现.
主要成果:
- 成功合成了一种深紫色,对空气和水分敏感的西拉斯坦 (1,1-bis[di-tert-butyl(methyl) silyl]-2,2-bis(2,4,6-triisopropylphenyl)-1-sila-2-stannaethene).
- X射线晶体学揭示了一种跨曲结构,具有特定的键长和角度 (Si=Sn键长:2.4188(14) Å,Si曲角度:26.2°,Sn曲角度:9.6°,扭曲角度:34.6°).
- 实验和理论数据表明极性Siδ−=Snδ+双键,影响反应性.
结论:
- 一种具有Si=Sn双键的新型西拉斯坦已经合成并进行了结构性特征.
- 横曲几何学和结合特性为-锡多重结合提供了基本的见解.
- 观察到的Si=Sn键的极性决定了加法反应中的区域选择性,通过理论计算验证.
相关概念视频
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