电流发光装置具有红色和绿色排放之间的可逆切换
S Welter1, K Brunner, J W Hofstraat
1Molecular Photonics Group, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.
Nature
|January 4, 2003
概括
研究人员使用半导体聚合物和复合物开发了一种新的有机电发光装置. 这种材料可以通过简单地改变应用电压来实现绿色和红色光辐射之间的可逆切换.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 光物理学的光学物理学
背景情况:
- 有机电光发射 (OEL) 研究优先考虑光发射器,以提高效率和稳定性.
- 开发新材料对于提高OEL设备性能至关重要.
研究的目的:
- 制造一个简单的OEL设备,具有电压依赖的双色发射.
- 为了研究一个半导体聚合物与光复合物相结合,用于可调节的光输出.
主要方法:
- 使用多乙烯 (PPV) 衍生物与二核复合物合的OEL装置的制造.
- 利用复合体作为三重发射器和电子转移媒介.
- 应用前向 (+4V) 和反向 (-4V) 偏差来控制排放颜色.
主要成果:
- 该装置在绿色和红色光辐射之间显示出完全可逆的电压依赖的切换.
- 前进偏差导致了复合体的红色发射.
- 反向偏差导致了聚合物宿主通过逐步电子转移机制发出绿色辐射.
结论:
- 通过电压调节成功制造了一个简单的OEL设备,显示双色发射.
- 双核复合体在调节电子转移和使可调节的发射成为可能方面发挥着关键作用.
- 这种方法为开发具有可控制光输出的先进OEL材料提供了有前途的途径.
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