在内马特液晶中观察表面和散体相变的观测
M I Boamfa1, M W Kim, J C Maan
1NSRIM Institute and High Field Magnet Laboratory, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands. boamfa@sci.kun.nl
Nature
|January 10, 2003
概括
研究人员观察到液晶 (LC) 中明显的表面相位过渡,与散装过渡分开. 这一发现提升了对表面LC行为的理解,这对LC显示技术至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 表面科学是一门学科.
背景情况:
- 液晶 (LC) 分子在表面上的行为是相变,湿现象和LC显示操作的关键.
- 由于过渡温度的接近,在液晶体中区分表面和散装相变具有挑战性.
研究的目的:
- 观察和描述一个纯的同位素-内马特 (IN) 表面相位过渡.
- 为了研究基板 anchoring 能量和磁场对表面的影响.
- 了解在内马特LC中表面和散体过渡的分离.
主要方法:
- 采用了阴性LC混合物来诱导表面组成的变化,将表面和散装过渡分开.
- 作为基板和应用磁场的函数,研究了同otropic-nematic表面相位过渡.
- 分析了表面IN过渡的顺序,基于表面固能量.
主要成果:
- 观察到一种纯同位素-阴性 (IN) 表面相转换,与大量IN转换不同.
- 表面IN过渡在弱表面是第一阶段的,在强表面是连续的.
- 应用的磁场没有改变表面的IN过渡温度,但增加了大部分的IN过渡温度.
结论:
- 这项研究成功地分离并描述了液晶中的表面和散装同位素-阴性过渡.
- 表面IN转换的性质 (第一阶段与连续) 取决于表面的固定能量.
- 磁场对体积和表面过渡有不同的影响,这归因于磁场诱导的表面湿层的秩序.
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