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相关的层结构:一种新型的液晶相,具有二维格子
Marko Prehm1, Siegmar Diele, Malay K Das
1Martin-Luther-University Halle-Wittenberg, Institute of Organic Chemistry, Kurt-Mothes Strasse 2, Germany.
Journal of the American Chemical Society
|January 16, 2003
概括
研究人员开发了一种新的液晶分子,由四个不同的部分组成. 这种新型材料自组织成一个独特的二维柱状液晶相.
科学领域:
- 材料科学 材料科学 材料科学
- 超分子化学 超分子化学
- 液晶是一种液晶.
背景情况:
- 设计具有多个不兼容部分的复杂分子在预测自我组装方面存在挑战.
- 液晶材料具有常规液体和固体晶体之间的特性,具有可调节的特性.
研究的目的:
- 为了合成和表征一种具有明显功能部分的新型四元五块分子.
- 为了研究自我组织行为,并确定由此产生的液晶相.
主要方法:
- 一个复杂的五块分子的合成,其中包括一个双核,二基基团和一个半化链.
- 使用偏光光学显微镜,差分扫描热度计和对齐样本的X射线衍射进行表征.
主要成果:
- 证实了一种具有二维 (2D) 格子的新型液晶相,被确定为柱状半相.
- 柱状中相由层的位置相关性引起,由分子组件的分离驱动.
- 详细的结构分析揭示了二核,结网和化/化链段在分层结构中的分离.
结论:
- 合成的四元五块分子自组织成一个独特的二维柱状液晶相.
- 观察到的相位行为归因于不兼容的分子段的复杂分离,包括芳香核,极群和化/碳化合物链.
- 本研究展示了一种通过分子设计设计设计复杂的液晶材料的策略,这些材料具有量身定制的等级结构.
相关概念视频
Structures of Solids
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
Ionic Crystal Structures
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Metallic Solids
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Network Covalent Solids
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Lattice Centering and Coordination Number
The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
Types of Unit Cells
Imagine taking a large number of identical...
Unit Cells
A crystal's internal structure is an orderly array of atoms, ions, or molecules, and the details of this array significantly influence the solid's properties. In a crystal, periodically repeating 'structural motifs' - which could be atoms, molecules, or groups thereof - create a 'space lattice.' This is essentially a three-dimensional, infinite array of points, each surrounded by its neighbors in an identical way, forming the basic structure of the crystal.A 'unit cell' is a theoretical...

