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Updated: Jul 10, 2026

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
14:44

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR

Published on: December 16, 2013

那么,J(Si-H) 的NMR合常数真的是一个探测非经典的H-Si相互作用存在的探针吗?

Stuart R Dubberley1, Stanislav K Ignatov, Nicholas H Rees

  • 1Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, UK.

Journal of the American Chemical Society
|January 16, 2003
PubMed
概括

研究人员合成了的化复合物,并观察到化连接常数随着替代的变化而显著增加. DFT计算显示,这种趋势与债券强度无关,对于n=1.1.而言,相互作用最强.

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