重原子同位素对来自Bacillus subtilis的氧酸盐脱碳酶催化反应的影响

Laurie A Reinhardt1, Drazenka Svedruzic, Christopher H Chang

  • 1Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA.

概括

氧沙酸脱碳酶 (OxDC) 使用和二氧化碳来切割氧沙酸,产生酸盐和二氧化碳. 动态同位素效应表明了涉及氧沙酸盐和甲酸盐中间体的激进机制.

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