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Updated: Jul 14, 2026

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Ab initio分子轨道研究铜中GGG三重体的G-选择性 (I) 介导的一电子氧化

Yasunori Yoshioka1, Hiroko Kawai, Tomoko Sato

  • 1Chemistry Department for Materials, Faculty of Engineering, Mie University, Tsu, Mie 514-8507, Japan. yyoshi@chem.mie-u.ac.jp

Journal of the American Chemical Society
|February 13, 2003
PubMed
概括

铜(I) 离子在DNA序列中选择性地破坏第一个关氨酸 (G(1)),如5'-TG(1) G(2) G(3) - 3'. 在铜媒介氧化中这种G(1) -选择性是由于稳定的铜协调和GGG三重体内的孔迁移.

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