具有可移动核心的单分散核心外球体合体的合成和表征
Kaori Kamata1, Yu Lu, Younan Xia
1Department of Chemistry, University of Washington, Seattle, WA 98195, USA.
Journal of the American Chemical Society
|February 27, 2003
概括
研究人员创建了新的核心-双纳米粒子与黄金核心和/聚合物外. 选择性去除二氧化产生了带有可移动黄金芯的空心聚合物珠,可用于测量粒子特性和扩散动力学.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 合体化学 合体化学
背景情况:
- 核心外纳米粒子在各种应用中至关重要.
- 开发复杂纳米结构的受控合成方法是必不可少的.
研究的目的:
- 合成金纳米颗粒被和聚合物外覆盖.
- 为了创建有可移动金芯的空心聚合物珠子.
- 证明这些结构对于描述和研究运输属性的有用性.
主要方法:
- 通过sol-gel方法对金纳米颗粒与无形二氧化进行符合性涂层.
- 表面移植,原子转移激素聚合,用于有机聚合物外的形成.
- 使用水性酸 (HF) 选择性去除二氧化层.
主要成果:
- 成功制造了具有可调节外厚度 (几十到几百纳米) 的核心双纳米粒子.
- 在蚀后开发了含有可移动金芯的空心聚合物珠.
- 证明了用于测量聚合物外厚度的电子反射.
- 利用金芯等离子体共振作为扩散动力学研究的光学探头.
结论:
- 合成的核心-双外和空心聚合物-金芯颗粒为纳米尺度测量提供了一个多功能平台.
- 空洞粒子系统能够精确地描述特征大小和传输特性.
- 黄金芯的光学特性是监测扩散等动态过程的有效工具.
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