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Updated: Jul 18, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

胺环在C(5) 位置的质子化:形成一个稳定的阴离子西格玛复合体

Adám Demeter1, Csaba Wéber, János Brlik

  • 1Gedeon Richter Ltd., Budapest 10, P.O. Box 27, H-1475 Hungary. a.demeter@richter.hu

Journal of the American Chemical Society
|February 27, 2003
PubMed
概括

这项研究揭示了2,4,6-胺三胺,N,N,N',N',N",N"-甲基-可以在N(1) 和C(5) 两种位置都能质子化. 还形成了一个新型衍生品,在C(5) 位置具有独特的质子.

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