氨和金属-氨溶液的结构研究
Helen Thompson1, Jonathan C Wasse, Neal T Skipper
1Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK.
Journal of the American Chemical Society
|February 27, 2003
概括
/同位素替代揭示了氨溶剂结构的变化. 添加会破坏键,形成溶解和金属溶液中的空隙.
科学领域:
- 物理化学 物理化学
- 解决方案化学 解决方案化学
- 材料科学 材料科学 材料科学
背景情况:
- 氨是一种独特的溶剂,具有广泛的键.
- 了解金属氨溶液中的溶解结构对于材料科学至关重要.
- 之前的研究缺乏关于这些解决方案的详细结构信息.
研究的目的:
- 为了研究纯氨和-氨溶液的溶剂结构.
- 为了量化金属添加时气结合的破坏.
- 为了阐明这些系统中的溶解结构和空隙形成.
主要方法:
- /同位素替代技术.
- 经典的三维计算机建模.
- 分析辐射分布函数和协调号码的分析.
主要成果:
- 纯氨在每个原子中约有2.0个键 (N-H距离:2.4A).
- 添加显著破坏了结合,将其降低到~0.7个键/N在8mol%的金属和0.0在21mol%.
- 确定了一个明确的第二个阴离子溶解,其中原子位于主要四面体阴离子周围. 在添加金属时形成空隙 (2.5-3.0 A半径).
结论:
- 该研究为氨溶液提供了详细的结构见解.
- /替代有效地探测溶剂结构和金属诱导的变化.
- 这些发现支持这些溶液中极子腔和道的理论预测.
相关概念视频
Halogens
Group 17 elements, known as halogens, are nonmetals. At room temperature, fluorine and chlorine are gases, bromine is a liquid, and iodine a solid. Astatine is a highly unstable radioactive element, so currently, most of its properties are unknown due to its short half-life. Tennessine is a synthetic element also predicted to be in this group.
Lewis Structures of Molecular Compounds and Polyatomic Ions
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Metallic Solids
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Structure of Amines
The hybridized nitrogen atom in amines possesses a lone pair of electrons and is bound to three substituents with a bond angle of around 108°, which is less than the tetrahedral angle of 109.5°. However, the C–N–H bond angle is slightly larger at 112°, with a carbon–nitrogen bond length of 147 pm. This carbon–nitrogen bond length of of amines is longer than the carbon–oxygen bond of alcohols (143 pm) but shorter than alkanes’ carbon–carbon bond (154 pm). These aspects are illustrated in Figure...


