在水中的二氧化碳微乳液
C Ted Lee1, Won Ryoo, P Griffin Smith
1Department of Chemical Engineering, University of Texas at Austin, Austin, Texas 78712, USA.
Journal of the American Chemical Society
|March 6, 2003
概括
二氧化碳在水中膨胀PFPE-K微粒,形成新的CO2在水中的微乳液. 这些微乳液增强了烯的溶解性,可以溶解脂性和性物质.
科学领域:
- 合体和表面科学科学
- 材料化学 材料化学
- 物理化学 物理化学
背景情况:
- perfluoropolyether carboxylates (PFPE-K) 在水溶液中形成圆柱状的小粒.
- 二氧化碳 (CO2) 可以与状结构相互作用并加以修改.
研究的目的:
- 为了研究液态和超临界CO2对PFPE-K微粒的影响.
- 为了描述产生的CO2在水中的微乳液 (C/W).
- 评估这些新型微乳液的溶解能力.
主要方法:
- 在水中形成PFPE-K微粒.
- 使用液态和超临界CO2的微粒胀.
- 通过光谱学分析微粒尺寸.
- 确定烯溶解性的方法.
- 在微乳液中探究烯定位的研究.
主要成果:
- CO(2) 显著膨胀PFPE-K微粒从20nm到80nm在约8.8的CO(2):表面活性剂比率 (R(CO2) 的显著膨胀.
- 在胀的粒 (C/W微乳液) 中,烯溶解度增加了大约10倍.
- 光数据表明,烯主要是与细胞核的隔离物.
结论:
- 新型CO2在水中的微乳液 (C/W) 是通过将PFPE-K片与CO2膨胀而形成的.
- 这些C/W微乳液对烯等脂性物质具有增强的溶解能力.
- 这项研究证明了C/W微乳液对脂友和友化合物的同时溶解的潜力.
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