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Protease- and Acid-catalyzed Labeling Workflows Employing 18O-enriched Water
09:43

Protease- and Acid-catalyzed Labeling Workflows Employing 18O-enriched Water

Published on: February 20, 2013

高压研究. 高压研究. XX. XX. XX. XX. XX. XX. XX. XX. XX. XX. XX. XX. 乙-α-chymotrypsinsins 的脱氧化

R C Neuman, D Owen, G D Lockyer

    Journal of the American Chemical Society
    |May 22, 1976
    PubMed
    概括

    No abstract available in PubMed .

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    Alkynes to Carboxylic Acids: Oxidative Cleavage02:01

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    Alkynes undergo oxidative cleavage in the presence of oxidizing reagents like potassium permanganate and ozone. The triple bond — one σ bond and two π bonds — is completely cleaved, and the alkyne is oxidized to carboxylic acids. When warm and basic aqueous potassium permanganate is used as an oxidizing agent, alkynes are first converted to carboxylate salts via an unstable α-diketone intermediate. Further, a mild acid treatment protonates the carboxylate anions generating free carboxylic acid...