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在FeII(CN) 6 4感应TiO2纳米颗粒中的界面电子转移:通过电吸光谱学研究直接电荷注入

Mikhail Khoudiakov1, Alejandro R Parise, Bruce S Brunschwig

  • 1Department of Chemistry, Brookhaven National Laboratory, P.O. Box 5000, Upton, NY 11973-5000, USA.

Journal of the American Chemical Society
|April 10, 2003
PubMed
概括

电吸光谱学揭示了TiO2纳米粒子上的染料敏感化Fe ((II) ((CN) 6 ((4-)) 复合体中的界面电子转移. 电子注入发生在局部的Ti位点,而不是非局部的波段,其传输距离为5.3 Å.

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