远程跳跃与逐步跳跃:磁场对光导聚合物薄膜的电荷转移光效应的影响
Fuyuki Ito1, Tadaaki Ikoma, Kimio Akiyama
1Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan.
Journal of the American Chemical Society
|April 17, 2003
概括
磁场揭示有机薄膜中的电荷转移动态. 该研究表明,自旋保守的洞跳是光导性的关键,磁场对光效应的影响证实了这一点.
科学领域:
- 有机电子学有机电子学
- 光导性机制的光导性机制
- 电荷转移物理学的物理.
背景情况:
- 了解电荷传输对于有机电子来说至关重要.
- 电荷转移 (CT) 光是有机无形固体中的一个关键现象.
- 磁场效应可以探测电荷传输中的自旋动力学.
研究的目的:
- 调查磁场对多化聚乙烯 (N-乙烯基碳酸) 薄膜中的CT光效应的影响.
- 阐明光导有机无形固体中初级电荷传输过程.
- 确定孔跳和内部隔离的机制.
主要方法:
- 由1,2,4,5-四亚二胺合聚 ((N-乙烯基碳醇)) 制成的薄膜制剂.
- 在变化的磁场 (高达50mT) 下测量电荷转移光.
- 使用超精密合和交叉路口机制进行分析.
- 基于逐步跳跃模型和Onsager分析的模拟.
主要成果:
- 图像扫描仪光度随着磁场的增加增加到10mT.
- 观察到CT光度的下降在40-50mT左右.
- 发现了旋转保守的阶段性洞跳的证据.
- 模拟的边界距离与Onsager估计的内部离散相一致.
结论:
- 步进式孔跳是这些片中的主要电荷传输机制.
- 观察到的磁场效应与高精度合和交叉路口机制相一致.
- 该研究提供了对有机无形固体光导性基本过程的洞察.
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