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导电聚合物的化学光刻,使用无痕可移组

Horacio J Salavagione1, María C Miras, César Barbero

  • 1Universidad Nacional de Río Cuarto, Departamento de Química, Agencia postal #3, 5800-Río Cuarto, Argentina.

Journal of the American Chemical Society
|May 2, 2003
PubMed
概括

化聚氨,来自聚氨,是可溶的,形成薄膜. 这使得一种简单的化学光刻技术能够创建导电型聚氨素图像.

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Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation