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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
08:12

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

使用尼特罗斯二烯对α-aminooxy和α-hydroxy ketone进行催化式enantioselective合成

Norie Momiyama1, Hisashi Yamamoto

  • 1Department of Chemistry, University of Chicago, 5735 South Ellis Avenue, Illinois 60637, USA.

Journal of the American Chemical Society
|June 6, 2003
PubMed
概括

一种新型的催化方法使得使用 (R) -BINAP-银复合物实现了高度酶选择性酸醇反应. 这种方法有效地合成了氨基氧基,这是有价值的高纯度的α-基的前体.

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