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Updated: Jul 18, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

氧气激活由非黑米铁 (II) 复合物:α-基托碳酸盐与碳酸盐相比

Mark P Mehn1, Kiyoshi Fujisawa, Eric L Hegg

  • 1Department of Chemistry and Center for Metals in Biocatalysis, 207 Pleasant Street Southeast, University of Minnesota, Minneapolis, MN 55455, USA.

Journal of the American Chemical Society
|June 26, 2003
PubMed
概括

铁复合物与α-碳酸盐激活氧气,模仿非血铁氧酶. 这些模型经过基化和氧化脱碳化,揭示了α-基团在氧激活中的关键作用.

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Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron07:56

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Oxidation of Alcohols02:37

Oxidation of Alcohols

In this lesson, the oxidation of alcohols is discussed in depth. The various reagents used for oxidation of primary and secondary alcohols are detailed, and their mechanism of action is provided.
The process of oxidation in a chemical reaction is observed in any of the three forms:
Oxidations of Aldehydes and Ketones to Carboxylic Acids01:15

Oxidations of Aldehydes and Ketones to Carboxylic Acids

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Loss of Carboxy Group as CO2: Decarboxylation of β-Ketoacids01:02

Loss of Carboxy Group as CO2: Decarboxylation of β-Ketoacids

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Reactivity of Enolate Ions01:23

Reactivity of Enolate Ions

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Oxidation of Phenols to Quinones01:17

Oxidation of Phenols to Quinones

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Enolate Mechanism Conventions01:15

Enolate Mechanism Conventions

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C-attack...