通过近红外吸收来探测大气中的水模度
K Pfeilsticker1, A Lotter, C Peters
1Institut für Umweltphysik, INF 229, University of Heidelberg, D-69120 Heidelberg, Germany.
概括
研究人员使用长途光谱学检测到水二极管 (WDs). 这一发现促进了大气光化学和气候研究中WDs的理解.
科学领域:
- 大气化学 大气化学
- 频谱学是一种光谱学.
- 分子物理学 分子物理学
背景情况:
- 水二次体 (WDs) 是水分子的弱键对.
- 工业气体可能会影响光化学和气候.
- 与水单体 (WM) 的光谱重叠阻碍了WD检测.
研究的目的:
- 为了测量水的吸收度,二度仪.
- 为了检测OH拉伸模式,WDs的超音调过渡.
主要方法:
- 大气长途差异光学吸收光谱 (18.34公里).
- 测量近红外OH拉伸模式的高音过渡.
主要成果:
- 在749.5nm观察到的WD吸收带.
- 半最大全宽度 (FWHM) 约为19.4厘米-1.4厘米.
- 带强度估计在1.23 x 10-22和5.25 x 10-22厘米/分子之间.
结论:
- 观察到的光谱特征与已知的WD属性保持一致.
- 这种检测为大气和气候模型提供了关键数据.
- 促进了对水二极管在大气过程中的作用的理解.
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