双[三甲基) 氨基],一种不稳定的双价化合物
Gyu-Hwan Lee1, Robert West, Thomas Müller
1Department of Chemistry, Hannam University, Taejon 305-761, Korea.
Journal of the American Chemical Society
|July 3, 2003
概括
研究人员通过减少合成了一种新的化合物, bis ((trimethylsilyl) silylene. 这种不稳定的烯使用低温NMR光谱学进行了鉴定,并与酒精反应,证实了其反应性.
科学领域:
- 有机化学 有机化学
- 低温合成 低温合成
- 谱光学表征的表征方法
背景情况:
- 西利烯是碳与双价的碳的类型.
- 低坐标化合物的合成和表征是具有挑战性的,因为它们固有的不稳定性.
- 之前的研究主要集中在和锡的类似物上,使得的对应物更少被探索.
研究的目的:
- 为了合成和表征一种新型的烯化合物, bis ((trimethylsilyl) 烯.
- 为了研究这种烯在低温下的稳定性和反应性.
- 为了比较基烯与其更重的14组同胞的特性.
主要方法:
- 在低温 (-78°C) 中使用石墨减少化前体.
- 溶液状态核磁共振 (NMR) 光谱,特别是29Si NMR,用于表征.
- 使用酒精 (甲醇和) 的低温捕获实验.
主要成果:
- 成功合成目标烯,二三甲) 烯,表示为1.
- 化合物1表现出不稳定性,但可以在低温下在溶液中进行研究.
- 29Si NMR 1 的化学转移在 223.9 ppm 测量,与理论计算一致.
- 与甲醇和的反应产生了预期的捕获产品,[(Me3Si) 2N]2Si(H) OR.
结论:
- 二甲三甲) 烯的合成可以通过还原方法实现.
- 该化合物是一种反应性中间体,表现出特有的烯化学特性.
- 低温NMR光谱为研究这种不稳定的物种提供了一种可行的方法.
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