第一个Au(I) -X-Ag(I) 酸 (X = Cl 和 Br) 的例子
Ke Zhang1, Janardhana Prabhavathy, John H K Yip
1Department of Chemistry, The National University of Singapore, 10 Kent Ridge Crescent, 119260, Singapore.
Journal of the American Chemical Society
|July 10, 2003
概括
合成了新的金银离子,具有独特的Au4X4结构,封装了一种银离子. 这些新型化合物通过多种相互作用表现出稳定性,包括金属性和pi-pi结合.
科学领域:
- 无机化学 无机化学
- 有机金属化学 有机金属化学
- 超分子化学 超分子化学
背景情况:
- 黄金和白银复合物在催化和材料科学中至关重要.
- 离子是具有独特结合特性的反应性物种.
- 对多金属结构的探索为协调化学提供了新的途径.
研究的目的:
- 为了合成和表征新的金银离子.
- 研究由此产生的化合物的结构特征.
- 了解这些新复合体内的稳定相互作用.
主要方法:
- (mu-PAnP) ((AuX) 2) 与银六抗酸盐 (AgSbF6) 的反应.
- 用于结构确定的X射线晶体学.
- 用光谱分析进行表征.
主要成果:
- 成功合成了{[{mu-PAnP) }{AuX) ]2Ag}+SbF6-离子 (X = Cl, Br).这些离子中的一个是离子.
- 发现了一个前所未有的扭曲的Au4X4十二面体,封装了一个中心的Ag (I) 离子.
- 稳定相互作用的鉴定:金属友好的Au-Ag,芳香的pi-pi和Ag-X键.
结论:
- 这项研究提出了一种具有独特结构图案的新型金银离子类.
- 封装的银离子通过强大的分子间力量的结合来稳定.
- 这些发现扩大了聚金属化合物及其潜在应用的范围.
相关概念视频
Chemical Reactions in Aqueous Solutions
Chemical substances interact in many different ways. Certain chemical reactions exhibit common patterns of reactivity. Due to the vast number of chemical reactions, it becomes necessary to classify them based on the observed patterns of interaction.
Ions as Acids and Bases
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Lewis Acids and Bases
In 1923, G. N. Lewis proposed a generalized definition of acid-base behavior in which acids and bases are identified by their ability to accept or to donate a pair of electrons and form a coordinate covalent bond.
A coordinate covalent bond (or dative bond) occurs when one of the atoms in the bond provides both bonding electrons. For example, a coordinate covalent bond occurs when a water molecule combines with a hydrogen ion to form a hydronium ion. A coordinate covalent bond also results when...
A coordinate covalent bond (or dative bond) occurs when one of the atoms in the bond provides both bonding electrons. For example, a coordinate covalent bond occurs when a water molecule combines with a hydrogen ion to form a hydronium ion. A coordinate covalent bond also results when...
Formation of Complex Ions
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
Precipitation of Ions
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
Lewis Acids and Bases
This lesson delves into Lewis acids and bases in the context of the octet rule for electron-deficient compounds. Here, the concept is discussed, emphasizing the group 13 elements like boron or aluminium. Since group 13 elements possess three valence electrons, they form trivalent compounds with a sextet of electrons and a vacant orbital for the central atom. Consequently, these electron-deficient compounds accept electrons from other species to complete their octet in a chemical reaction. They...


