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相关概念视频

Complexation Equilibria: The Chelate Effect01:19

Complexation Equilibria: The Chelate Effect

1.2K
In complexation reactions, metal atoms or cations interact with ligands to form donor-acceptor adducts called metal complexes. Ligands that bind through one donor site are monodentate, ligands with two donor sites are bidentate, and those with more than two donor sites are polydentate ligands. For example, ethylene diamine is a bidentate ligand that binds through two nitrogen donor atoms, forming a five-membered ring. EDTA is a polydentate ligand that binds through four oxygen and two nitrogen...
1.2K
Complexation Equilibria: Factors Influencing Stability of Complexes01:09

Complexation Equilibria: Factors Influencing Stability of Complexes

806
In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
806
Ion Exchange01:17

Ion Exchange

1.2K
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
1.2K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

48.8K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
48.8K
Formation of Complex Ions03:45

Formation of Complex Ions

25.8K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
25.8K
Complexation Equilibria: Overview01:23

Complexation Equilibria: Overview

1.3K
Complexation reactions take place when dative or coordinate covalent bonds form between metal ions and ligands. The compounds formed in these reactions are called coordination compounds. The number of bonds formed between the metal ion and the ligands is called its coordination number. Generally, most metal ions in an aqueous solution are solvated by water molecules and thus exist as aqua complexes.
The equilibrium constant of the complexation reaction is represented as the formation constant...
1.3K

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Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides
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在24+个阴阳宿主中的阴阳客.

Jean-Pascal Bourgeois1, Makoto Fujita, Masaki Kawano

  • 1Department of Applied Chemistry, School of Engineering, The University of Tokyo, CREST, Japan Science and Technology Corporation (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

Journal of the American Chemical Society
|August 2, 2003
PubMed
概括

研究人员创造了一种新的协调子,能够封装 cationic 客人,由于其自身的正电荷,挑战预期. 在宿主-客人化学中的这一突破揭示了一种类似洋的结构,促进了离子-离子相互作用.

科学领域:

  • 超分子化学 超分子化学
  • 协调化学 协调化学
  • 材料科学 材料科学 材料科学

背景情况:

  • 协调是一种超分子结构,在宿主-客人化学中具有潜在的应用.
  • 了解主机-客户系统中的电荷相互作用对于设计新功能材料至关重要.

研究的目的:

  • 通过二皮里米丁连接体和 (II) 合成一种新的四面体协调子.
  • 为了研究新制备的子的宿主-客人化学,特别是它结合阴性客人的能力.

主要方法:

  • 从线性二甲胺连接体 (L) 和cis-protected (II) (M) 中合成M12L6协调.
  • 宿主-客人化学研究以确定子的结合能力.
  • 结构分析以阐明复杂的形成和相互作用.

主要成果:

  • 成功合成了一种新的M12L6四面体协调.
  • 子表现出前所未有的宿主-客人化学反应,尽管具有高度积极的框架电荷 (+24),但可以容纳阴性客人.
  • 鉴定出一种类似洋的外结构,通过反洋调解-相互作用.

结论:

  • 子M12L6表现出独特的子-子宿主-客人相互作用,挑战了以前的理解.

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  • 这种类似洋的结构图案是稳定这些不寻常的复合体的关键.
  • 这项工作为设计具有量身定制的电荷相互作用的超分子系统开辟了新的途径.