Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Strong Acid and Base Solutions03:22

Strong Acid and Base Solutions

A strong acid is a compound that dissociates completely in an aqueous solution and produces a concentration of hydronium ions equal to the initial concentration of acid. For example, 0.20 M hydrobromic acid will dissociate completely in water and produces 0.20 M of hydronium ions and 0.20 M of bromide ions.
Weak Acid Solutions04:02

Weak Acid Solutions

Few compounds act as strong acids. A far greater number of compounds behave as weak acids and only partially react with water, leaving a large majority of dissolved molecules in their original form and generating a relatively small amount of hydronium ions. Weak acids are commonly encountered in nature, being the substances partly responsible for the tangy taste of citrus fruits, the stinging sensation of insect bites, and the unpleasant smells associated with body odor. A familiar example of a...
Mixtures of Acids03:27

Mixtures of Acids

The pH of a solution containing an acid can be determined using its acid dissociation constant and its initial concentration. If a solution contains two different acids, then its pH can be determined using one of several methods depending upon the relative strength of the acids and their dissociation constants.
A Mixture of a Strong Acid and a Weak Acid
In a mixture of a strong acid and a weak acid, the strong acid dissociates completely and becomes a source of almost all the hydronium ions...
Acid Strength and Molecular Structure03:05

Acid Strength and Molecular Structure

Binary Acids and Bases
In the absence of any leveling effect, the acid strength of binary compounds of hydrogen with nonmetals (A) increases as the H-A bond strength decreases down a group in the periodic table. For group 17, the order of increasing acidity is HF < HCl < HBr < HI. Likewise, for group 16, the order of increasing acid strength is H2O < H2S < H2Se < H2Te. Across a row in the periodic table, the acid strength of binary hydrogen compounds increases with increasing...
Balancing Redox Equations02:58

Balancing Redox Equations

Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
Mixtures of Acids01:19

Mixtures of Acids

The pH of a solution containing an acid can be determined using its acid dissociation constant and initial concentration. If a solution contains two different acids, then its pH can be determined using one of several methods depending on the relative strength of the acids and their dissociation constants.
In a strong and weak acid mixture, the strong acid dissociates completely and becomes a source of almost all the hydronium ions present in the solution. In contrast, the weak acid shows...

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Wavelength-Dependent Nitrogen Fixation and Hydrogenation to Ammonia over Lithium Hydride Catalyst.

Journal of the American Chemical Society·2026
Same author

Molecular Design of Crystalline Potassium Pyridonate Electrolytes for All-Solid-State Potassium Metal Batteries.

Journal of the American Chemical Society·2026
Same author

The Sequential C<sub>2</sub> Addition Formation Mechanism of [6,6] Fullertube C<sub>36+36+12</sub> <sub>n</sub> Series: A Theoretical Study.

Journal of computational chemistry·2025
Same author

Non-IPR Fullertube Series C<sub>10+10+6<i>n</i></sub> : A Theoretical Prediction.

ACS omega·2025
Same author

Elucidating Structures of Complex Organic Compounds Using a Machine Learning Model Based on the <sup>13</sup>C NMR Chemical Shifts.

Precision chemistry·2025
Same author

Fabrication of atomically dispersed barium hydride catalysts for the synthesis of deuterated alkylarenes.

Nature communications·2025

相关实验视频

Updated: Jul 10, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

在醇的臭氧化中HOOO(-) 离子的作用:在气相和溶液相机制中存在很大的差异.

Anan Wu1, Dieter Cremer, Bozo Plesnicar

  • 1Department of Theoretical Chemistry, Göteborg University, Reutersgatan 2, S-413 20 Göteborg, Sweden.

Journal of the American Chemical Society
|August 2, 2003
PubMed
概括

研究臭氧与异醇反应的研究揭示了不同的气相和溶液相机制. 溶液阶段涉及化物转移和独特的HOOO(-) 离子,解释产品分布并告知臭氧毒性.

科学领域:

  • 计算化学是一种计算化学.
  • 反应机制的反应机制
  • 臭氧的化学成分

背景情况:

  • 臭氧化是一个关键的氧化过程.
  • 了解酒精臭氧化机制至关重要.
  • 臭氧的反应性在气相和溶液相之间有很大差异.

研究的目的:

  • 为了阐明异醇臭氧化的反应机制.
  • 为了比较气相和溶液相路径.
  • 调查中间体的作用及其对产品分销的影响.

主要方法:

  • 利用了二次多体扰动理论.
  • 使用密度函数理论 (DFT) 与B3LYP混合函数.
  • 应用了一个全面的6-311++G(3df,3pd) 基础集,用于准确的能量计算.

主要成果:

  • 气相臭氧化主要由激素/双激素中间体进行.
  • 溶液相臭氧化具有化物转移和一个HOOO(-) 离子中间体.
  • HOOO(-) 离子的特性解释了在乙溶液中观察到的产品分布.

结论:

更多相关视频

In Situ Characterization of Boehmite Particles in Water Using Liquid SEM
11:59

In Situ Characterization of Boehmite Particles in Water Using Liquid SEM

Published on: September 27, 2017

In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework
11:38

In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework

Published on: February 1, 2020

相关实验视频

Last Updated: Jul 10, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

In Situ Characterization of Boehmite Particles in Water Using Liquid SEM
11:59

In Situ Characterization of Boehmite Particles in Water Using Liquid SEM

Published on: September 27, 2017

In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework
11:38

In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework

Published on: February 1, 2020

  • 在气相与溶液相之间,不同的机制控制着异醇臭氧化.
  • 在溶液相臭氧化中,HOOO(-) 离子起着至关重要的作用.
  • 这些发现有助于理解酒精臭氧化和臭氧毒性.