可能的热和化学稳定体中心立方铁在地球的核心
Lidunka Vocadlo1, Dario Alfè, M J Gillan
1Research School of Earth Sciences, Birkbeck College and University College London, UK. l.vocadlo@ucl.ac.uk
Nature
|August 2, 2003
概括
地球的内核可能包含一个以身体为中心的立方体 (bcc). 铁合金,而不是纯铁. 硫或等不洁物稳定了这个阶段,这可能解释了内部核心复杂性的地震观测.
科学领域:
- 地质物理学 地质物理学
- 材料科学 材料科学 材料科学
- 量子力学就是量子力学.
背景情况:
- 地球固体内核中铁的稳定阶段仍在争论中.
- 地震学数据表明,内部核心的复杂层次.
- 之前的理论倾向于六角密集包装 (hcp). 在核心压力下的铁.
研究的目的:
- 为了研究体中心立方体 (b.c.c.) 的稳定性. 铁在地球的内核条件.
- 为了确定温度和杂质对铁的晶体结构的影响.
- 为了使理论预测与地震学观测相协调.
主要方法:
- 使用ab initio分子动力学的量子力学研究.
- 自由能量计算以在核心压力和温度下建模行为.
- 对BCC的分析 和hcp的使用情况. 有或没有杂质的铁相.
主要成果:
- 身体中心立方体 (b.c.c.) 在核心温度下,铁在热带上稳定.
- 纯粹的hcp是什么意思 铁在热力学上更稳定.
- 硫或杂质稳定了BCC. 在hcp上进行相位. 第一个阶段. 阶段.
结论:
- 一种BCC结构的铁合金,而不是纯铁,是地球内核的强有力的候选者.
- 杂质在稳定BCC中起着至关重要的作用. 第一个阶段. 阶段.
- 这一发现为内核观察到的地震复杂性提供了潜在的解释.
更多相关视频
相关概念视频
Phase Transitions: Melting and Freezing
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
Nuclear Stability
Protons and neutrons, collectively called nucleons, are packed together tightly in a nucleus. With a radius of about 10−15 meters, a nucleus is quite small compared to the radius of the entire atom, which is about 10−10 meters. Nuclei are extremely dense compared to bulk matter, averaging 1.8 × 1014 grams per cubic centimeter. If the earth’s density were equal to the average nuclear density, the earth’s radius would be only about 200 meters.
To hold positively charged protons together in the...
To hold positively charged protons together in the...
Temperature and Thermal Equilibrium
Heat and temperature are essential concepts for everyone every day. The study of heat and temperature is part of an area of physics known as thermodynamics. It is not always easy to distinguish heat and temperature.
The concept of temperature has evolved from the common concepts of hot and cold. The scientific definition of temperature explains more than just our sense of hot and cold. Temperature is operationally defined as the quantity measured with a thermometer. Furthermore, temperature is...
The concept of temperature has evolved from the common concepts of hot and cold. The scientific definition of temperature explains more than just our sense of hot and cold. Temperature is operationally defined as the quantity measured with a thermometer. Furthermore, temperature is...
Ferromagnetism
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
Complexation Equilibria: Factors Influencing Stability of Complexes
In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
Microbes and Other Elemental Cycles
Microbial activity plays a pivotal role in the biogeochemical cycling of iron and manganese, especially at the redox gradients characteristic of stratified aquatic environments. These cycles are driven by microbial transformations between oxidized and reduced forms of the metals, allowing organisms to exploit them for metabolic energy and structural purposes.Iron Cycling Across Redox GradientsIn neutral, oxygen-rich surface waters, iron is predominantly found in its oxidized, insoluble ferric...


