铁催化烯通过H2O2的cis-dihydroxylation:电友性与核友性机制的电友性对比

Megumi Fujita1, Miquel Costas, Lawrence Que

  • 1Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA.

概括

这项研究区分了氨酸二氧化的非海姆铁催化剂. 类A催化剂表现出电友性行为,而类B催化剂表现出与不同中间体的核友性反应性.

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