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Deposition of Porous Sorbents on Fabric Supports
Published on: June 12, 2018
硫化微孔的有机-无机混合物作为强大的布朗斯特酸
Zhike Wang1, Joy M Heising, Abraham Clearfield
1Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA.
Journal of the American Chemical Society
|August 21, 2003
概括
研究人员使用创建了新的微孔无机有机混合体. 这些材料,当硫化时,表现出强烈的Bronsted酸性,显示出催化和分离的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 催化剂是一种催化剂.
背景情况:
- 微孔材料对于各种化学应用至关重要.
- 开发具有调节性质的新材料仍然是关键的研究领域.
- 无机有机混合物具有独特的结构和化学特征.
研究的目的:
- 合成和表征新的微孔无机有机混合物.
- 研究这些材料作为固体酸催化剂的潜力.
- 探索它们适用于分离和离子交换应用的适用性.
主要方法:
- 在DMSO/乙醇中,与4,4'-双和4,4'-二 (酸) 的反应.
- 在压力下使用三氧化硫 (SO3) 硫化得到的混合物.
- 使用BET分析对表面积和毛孔大小的表征.
- 通过 (13)C NMR光谱测量吸附子的酸度.
主要成果:
- 合成了微孔无机有机混合体,表面积高达400m(2) / g,孔径为10-20 Å.
- 硫化得到的材料的布朗斯特酸强度与100%的硫酸 (H(2) SO(4) 相当.
- 在温和的条件下,硫化混合物有效催化了子的凝结和裂变反应.
结论:
- 过多的有助于形成高表面积的微孔无机有机混合体.
- 硫化混合物由于其强烈的Bronsted酸性而表现出极好的催化活性.
- 这些新型材料在催化,分离和离子交换中具有有前途的应用,因为它们具有独特的孔隙结构和酸度.
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