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Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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甲基的直接和选择性的有机催化性α氧化

Sean P Brown1, Michael P Brochu, Christopher J Sinz

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|September 4, 2003
PubMed
概括

这项研究引入了一种新型的有机催化方法,用于直接对化物进行enantioselectiveα-氧化. 使用l-proline,这种方法可以有效地产生有价值的性α-oxyaldehydes用于合成.

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